Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Johnson 1875 on some remarkable changes produced in iron and steels by the action of hydrogen acids. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Common signs of hydrogen embrittlement are cracking of weldments and stress induced cracks. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. Sulfide stress cracking is prevented by minimizing the hardness and strength of the alloys. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. This is an embrittlement that is caused by liquid metals.
Figures 5 through 10 show the influence of hydrogen on steel 10. Sulfide stress cracking of steels it is generally accepted that ssc is a form of hydrogen embrittlement cracking in most high strength steels. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. Investigations of hydrogen embrittlement and sulfide stress cracking of nickel and nickelbase alloys have not been quite as extensive as in the case of steels. Sulfide stress corrosion cracking and hydrogen induced cracking of. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and. The material was sensitive to hydrogen embrittlement stress corrosion as a consequence of its microstructure. Mcintyre a bent beam test method for hydrogen sulfide stress corrosion cracking reslstanced. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Specifying valves for hydrogen service valve magazine.
Sulphide stress cracking is prevented by minimising the hardness and. The variation of the name is due to the lack of agreement in the mechanism of failure. Screening tests for hydrogen stress cracking susceptibilityw. Transverse sections of steels showing ssc cracks, after corrosion testing according to nace. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Some researchers consider sulfidestress cracking a type of stresscorrosion cracking, while others consider it a type of hydrogen embrittlement. With a tensile stress or stressintensity factor exceeding a specific threshold, the atomic hydrogen interacts with the metal to induce subcritical. This barcode number lets you verify that youre getting exactly the right version or edition of a book. Hydrogen embrittlement he a permanent loss of ductility in a metal or alloy caused b y hydrogen in combination with stress, either externally applied or internal residual stress 1. Hydrogen is present in minute quantities in steel, usually less than 1 part per million, but is attracted towards stress.
General aspects hydrogen embrittlement is usually understood as the unwanted delayed brittleness of. The role of hydrogen in sulfide stress cracking of low. Hydrogen can also be introduced during the fabrication andor welding of a steel component. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Embrittlement is a phenomenon that causes loss of ductility in a material, thus making it brittle. Examples of hydrogen embrittlement are cracking of weldments or hardened. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Sulfide stress cracking of nickelcontaining lowalloy steels. Pdf sulfide stress corrosion cracking and hydrogen induced. Hydrogen embrittlement characteristics, especially pertinent to sulfide stress cracking, or steels has been investigated to a great extent. When operating in a zone with h 2 s present, you must use equipment that is constructed of materials with metallurgical properties that resist or prevent sulfide stress cracking also known as hydrogen embrittlement, stress corrosion cracking, or h 2 s embrittlement, chloridestress cracking, hydrogeninduced cracking, and other failure modes.
The paper presents the results of a programme designed to define the material, stress and environmental factors controlling sensitivity of ferriticaustenitic stainless steels to hydrogen embrittlement stress cracking when exposed to. Investigation of the effect of low temperature aging on. Hydrogen embrittlement of steel industrial metallurgists. Hydrogen sulphide stress corrosion cracking in materials for. The result of hydrogen embrittlement is that components crack and fracture at stresses less than the yield strength of the metal. The reduction in hardness produces a reduction in strength. Hydrogen embrittlement and stress corrosion cracking. Corrosionpedia what is sulfide stress cracking ssc.
The effects of sulfide stress cracking on the mechanical properties. Hydrogen induced cracking of low strength steels in. We published this article under an openaccess license. Controlling hydrogen embrittlement in ultrahigh strength. Strategies for controlling hydrogen embrittlement are proposed based on the information generated. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular. Hydrogen embrittlement and relief treatment study of zinc phosphatecoated. Sulfide stress cracking is most severe at ambient temperature, particularly in the range of 20 to 120f 6 to 49c. Hydrogen embrittlement cracking of superduplex steel twi. Wet hydrogen sulfide h2s cracking inspectioneering. Sulfide stress cracking an overview sciencedirect topics. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis.
Hydrogen uptake is promoted in the presence of sulfides. A pitting type corrosion and sulfide stress cracking ssc. Admittedly, direct evidence to this effect is limited. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides. This is generally caused by hydrogen introduced into the steel from the environment after being placed in service. Hughes 1880 note on some effects produced by the immersion of steel and iron wires in acidulated water. Steels react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulphide stress cracking is a particular occurrence of hydrogen embrittlement at least for the alloys considered, and in the test conditions envisaged, where the hydrogen is generated as part of the cathodic corrosion reaction. Lower bake times resulted in quicker fracture times due to higher hydrogen content. Screening tests for hydrogen stress cracking susceptibilityw r crumly.
Stress cracking is a form of hydrogen embrittlement. Since sulfide stress cracking is essentially hydrogen embrittlement catalyzed by the presence of sulfide ions, nace mr0175iso 15156, petroleum and natural gas industries materials for use in h2scontaining environments in oil and gas production, andor nace mr0103, materials resistant to sulfide stress cracking in corrosive petroleum. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. At critical residual stress, the hydrogen induced cold cracking hicc occurs.
Atomic hydrogen either combines to form h 2 at the metal surface, or diffuses into the metal matrix. Figures 5 and 7 are a bar that was not cathodically treated, therefore, was. At present there are two main theories for sulfide corrosion cracking, namely hydrogen embrittlement mechanism and stress corrosion cracking mechanism. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Link to corrigendum together with my colleagues and good friends dr. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in. Figure 4 shows a vanadium wire that literally shattered when it was cathodically charged with hydrogen in an electrolytic cell 9. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. It is generally accepted that sulfide stress cracking ssc failures are the result of hydrogen embrittlement. The historical development of the understanding of sulfide stress cracking ssc is presented and the possible mechanisms and the significant parameters are discussed.
The purpose of this paper is to provide the experimental evidence which establishes the causality of hydrogen and the contributory roles of h 2 s and anodic dissolution. Pdf sulfide stress corrosion cracking and hydrogen. Generally, hydrogen embrittlement is classified under two broad categories based on the. A marked difference in material response under loadcontrol and displacementcontrol was observed. Hydrogen sulfide stress corrosion cracking in materials. Hydrogen embrittlement is a metals loss of ductility and reduction of load bearing capability due to the absorption of hydrogen atoms or molecules by the metal. In he as most people use the term, hydrogen is already present in the metal, eg from melting, pickling, etc. However, the evidence heretofore has been mostly circumstantial. Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. Mechanisms that have been proposed to explain embrittlement include the formation of brittle hydrides, the creation of voids that can lead to bubbles and pressure buildup within a material and e. Environmentally assisted cracking eac is a general term that includes processes such as stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme, and corrosion fatigue cf. Bend and tensile tests were conducted to establish the threshold condition for cracking in hubs on a subsea manifold subject to cathodic protection.
This is the embrittlement caused by the absorption of hydrogen sulfide. During preelectroplating, the cleaning and certain pickling solutions are more apt to introduce hydrogen into the steel. Hydrogen embrittlement embrittlement is a phenomenon that causes loss of ductility in a material, thus making it brittle. The manuscript can be downloaded following this link or directly. Environmental hydrogen embrittlement ehe is another form of hydrogen embrittlement. Besides this, the specimen ar, which has an unbalanced microstructure 64.
If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc the use of cathodic protection for corrosion protection if the process is not properly controlled. James watts provided you with some excellent tips for better control of the plating process. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Definition of sulfide stress cracking ssc iadc lexicon. Basic differences between sour service and sour corrosion are highlighted and the carbon dioxide to hydrogen sulfide ratios used to define sour corrosion are mentioned. Sulfide stress cracking ssc cracking of metal involving corrosion and tensile stress residual andor applied in the presence of water and h 2 s note ssc is a form of hydrogen stress cracking hsc and involves embrittlement of the metal by atomic hydrogen that is produced by acid corrosion on the metal surface. Avoiding stress cracking of ferritic austenitic steels twi. It should not be confused with the term stress corrosion cracking which is. In the absence of residual stress or external loading, environmental hydrogen embrittlement is manifested in various forms, such as blistering, internal cracking, hydride formation, and reduced ductility. Liquid metal crackinglmc, usually a physicochemical process.
If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc c. Materials such as highstrength steels, titanium, and aluminum alloys are the most susceptible to this type of failure. This is an embrittlement caused by diffusion of metal atoms, either liquid or solid, into the metal. Heat treatment baking was used to reduce hydrogen content. It was also reported that steel resistance to hydrogen embrittlement is largely. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951.
Hydrogen embrittlement relief and treatment wisconsin oven. The following paragraphs deal with this subject from a failure analysis point of view. Despite of this, the comparison of embrittlement parameters shows that the dss solution treated st was the less susceptible to sulfide stress corrosion cracking sscc. The most popular accepted method to help alleviate hydrogen embrittlement is with a process called, relief baking. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Section page tables iii figures iv definitions v acronyms vi foreword vii 1.
This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Sulfide stress cracking ssc vs hydrogen induced cracking. Hydrogen embrittlement the action of hydrogen as a result of sulfide corrosion. In fact, some authors 6 have used the term hydrogen embrittlement to refer to ssc.
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